Selected publications

The trouble with ODE: polymerization during nanocrystal synthesis
Evert Dhaene, Jonas Billet, Ellie Bennett, Isabel Van Driessche, Jonathan De Roo*
Nano Lett. 2019, 19, 10, 7411-7417; https://10.1021/acs.nanolett.9b03088

Probing Solvent–Ligand Interactions in Colloidal Nanocrystals by the NMR Line Broadening
De Roo, J.*; Yazdani, N.; Drijvers, E.; Lauria, A.; Maes, J.; Owen, J. S.; Van Driessche, I.; Niederberger, M.; Wood, V.; Martins, J. C.; Infante, I.; Hens, Z.
Chem. Mater.2018, 30, 5485-5492; https://doi.org/10.1021/acs.chemmater.8b02523

Synthesis of Phosphonic Acid Ligands for Nanocrystal Surface Functionalization and Solution Processed Memristors
De Roo, J.*; Zhou, Z.; Wang, J.; Deblock, L.; Crosby, A. J.; Owen, J. S.; Nonnenmann, S. S.*
Chem. Mater. 2018, 30 (21), 8034-8039; https://doi.org/10.1021/acs.chemmater.8b03768

Stabilization of colloidal Ti, Zr, and Hf oxide nanocrystals by protonated tri-n-octylphosphine oxide (TOPO) and its decomposition products
De Keukeleere, K.; Coucke, C.; De Canck, E.; Van Der Voort, P.; Delpech, F.; Coppel, Y.; Hens, Z.; Van Driessche, I.; Owen, J. S.; De Roo, J.*
Chem. Mater.2017, 29, 10233-10242; https://doi.org/10.1021/acs.chemmater.7b04580

Colloidal metal oxide nanocrystal catalysis by sustained chemically driven ligand displacement
De Roo, J.*; Van Driessche, I.; Martins, J. C.; Hens, Z.*
Nat. Mater.2016, 15 (5), 517-521; https://doi.org/10.1038/nmat455


Full list of publications

Resorcin [4] arene-based multidentate phosphate ligands with superior binding affinity for nanocrystal surfaces.Suren J Nemat, Dietger Van den Eynden, Loren Deblock, Michael Heilmann, Jesper M Köster, Mahsa Parvizian, Konrad Tiefenbacher*, Jonathan De Roo* DOI: 10.1039/D1CC00223F (Communication) Chem. Commun., 2021, Advance Article https://pubs.rsc.org/en/content/articlepdf/2021/cc/d1cc00223f

 

 

Atomically precise nanocrystals.
Hens, Z.*; De Roo. J.* Journal of the American Chemical Society (2020), 142 (37), 15627-15637.
https://pubs.acs.org/doi/abs/10.1021/jacs.0c05082

Anthracene Diphosphate Ligands for CdSe Quantum Dots; Molecular Design for Efficient Upconversion.
De Roo J.; Huang, Z.; Schuster, N. J.; Hamachi, L. S.; Congreve, D. N.; Xu, Z.; Xia, P.; Fishman, D. A.; Lian, T.; Owen, J. S.; Tang, M. L.Chem. Mat. 2020, 32 (4), 1461-1466.https://pubs.acs.org/doi/10.1021/acs.chemmater.9b04294

Scalable Approaches to Copper Nanocrystal Synthesis under Ambient Conditions for Printed Electronics
Oliva-Puigdomènech, A.; De Roo, J.*; Van Avermaet, H.; De Buysser, K.; Hens, Z.
ACS Applied Nano Materials (2020), 3 (4), 3523-3531. https://doi.org/10.1021/acsanm.0c00242

Continuous Nucleation and Size Dependent Growth Kinetics of Indium Phosphide Nanocrystals.
McMurtry, B. ;Qian, K.; Teglasi, J.; Swarnakar, A.; De Roo, J.; Owen, J.*
Chemistry of Materials (2020), 32 (10), 4358-4368. https://doi.org/10.1021/acs.chemmater.0c01561

The Trouble with ODE: Polymerization during Nanocrystal Synthesis
Dhaene E.; Billet J.; Van Driescche; De Roo J.
Nano Lett.2019, 19 (10), 7411-7417; https://doi.org/10.1021/acs.nanolett.9b03088

Ligand Binding to Copper Nanocrystals: Amines and Carboxylic Acids and the Role of Surface Oxides
Oliva-Puigdomènech, A.; De Roo, J.; Kuhs, J.; Detavernier, C.; Martins, J. C.; Hens, Z.
Chem. Mater. 2019, 31 (6), 2058-2067; https://doi.org/10.1021/acs.chemmater.8b05107

Ligand Displacement Exposes Binding Site Heterogeneity on CdSe Nanocrystal Surfaces
Drijvers, E.; De Roo, J.; Martins, J. C.; Infante, I.; Hens, Z.*
Chem. Mater. 2018, 30 (3), 1178-1186; https://doi.org/10.1021/acs.chemmater.7b05362

How Ligands Affect Resistive Switching in Solution-Processed HfO2 Nanoparticle Assemblies
Wang, J.; Choudhary, S.; De Roo, J.; De Keukeleere, K.; Van Driessche, I.; Crosby, A. J.; Nonnenmann, S. S.*
ACS Appl. Mater. Interfaces 2018, 10 (5), 4824-4830; https://doi.org/10.1021/acsami.7b17376

Stereoelectronic Effects on the Binding of Neutral Lewis Bases to CdSe Nanocrystals
Anderson, N. C.; Chen, P. E.; Buckley, A. K.; De Roo, J.; Owen, J. S.*
J. Am. Chem. Soc. 2018, 140, 7199-7205; https://doi.org/10.1021/jacs.8b02927

Light Absorption Coefficient of CsPbBr3 Perovskite Nanocrystals
Maes, J.; Balcaen, L.; Drijvers, E.; Zhao, Q.; De Roo, J.; Vantomme, A.; Vanhaecke, F.; Geiregat, P.; Hens, Z.*
J. Phys. Chem. Lett. 2018, 3093-3097; https://doi.org/10.1021/acs.jpclett.8b01065

Pair Distribution Function Analysis of ZrO2 Nanocrystals and Insights in the Formation of ZrO2-YBa2Cu3O7 Nanocomposites
Rijckaert, H.; De Roo, J.; Van Zele, M.; Banerjee, S.; Huhtinen, H.; Paturi, P.; Bennewitz, J.; Billinge, S.; Bäcker, M.; De Buysser, K.; Van Driessche, I.*
Materials2018, 11, 1066; https://doi.org/10.3390/ma11071066

Size Tunable Synthesis and Surface Chemistry of Metastable TiO2-Bronze Nanocrystals
Billet, J.; Dujardin, W.; De Keukeleere, K.; De Buysser, K.; De Roo, J.*; Van Driessche, I.*
Chem. Mater. 2018, 30 (13), 4298-4306; https://doi.org/10.1021/acs.chemmater.8b01296

Probing Solvent–Ligand Interactions in Colloidal Nanocrystals by the NMR Line Broadening
De Roo, J.*; Yazdani, N.; Drijvers, E.; Lauria, A.; Maes, J.; Owen, J. S.; Van Driessche, I.; Niederberger, M.; Wood, V.; Martins, J. C.; Infante, I.; Hens, Z.
Chem. Mater. 2018,30, 5485-5492; https://doi.org/10.1021/acs.chemmater.8b02523

Using Bulk-Like Nanocrystals to Probe Intrinsic Optical Gain Characteristics of Inorganic Lead Halide Perovskites
Geiregat, P.*; Maes, J.; Chen, K.; Drijvers, E.; De Roo, J.; Hodgkiss, J. M.; Hens, Z.
ACS Nano 2018, 12 (10), 10178-10188; https://doi.org/10.1021/acsnano.8b05092

Colloidal CdSe Nanoplatelets, a Model for Surface Chemistry/Opto-Electronic Property Relations in Semiconductor Nanocrystals
Singh, S.*; Tomar, R.; ten Brinck, S.; De Roo, J.; Geiregat, P.; Martins, J. C.; Infante, I.; Hens, Z.
J. Am. Chem. Soc. 2018, 140 (41), 13292-13300; https://doi.org/10.1021/jacs.8b07566

Synthesis of Phosphonic Acid Ligands for Nanocrystal Surface Functionalization and Solution Processed Memristors
De Roo, J.*; Zhou, Z.; Wang, J.; Deblock, L.; Crosby, A. J.; Owen, J. S.; Nonnenmann, S. S.*
Chem. Mater. 2018, 30 (21), 8034-8039; https://doi.org/10.1021/acs.chemmater.8b03768

The Surface Chemistry of Colloidal HgSe Nanocrystals, Towards Stoichiometric Quantum Dots by Design
Grigel, V.; Sagar, L. K.; De Nolf, K.; Zhao, Q.; Vantomme, A.; De Roo, J.; Infante, I.; Hens, Z.
Chem. Mater. 2018, 30 (21), 7637-7647; https://doi.org/10.1021/acs.chemmater.8b02908

Thermal processing of aqueous AZO inks towards functional TCO thin films
Vernieuwe, K.; Cuypers, D.; Kirschhock, C. E. A.; Houthoofd, K.; Vrielinck, H.; Lauwaert, J.; De Roo, J.; Martins, J. C.; Van Driessche, I.; De Buysser, K.*
J. Alloys Compd. 2017, 690, 360-368; https://doi.org/10.1016/j.jallcom.2016.08.120

Solution-Based Synthesis and Processing of Sn- and Bi-Doped Cu3SbSe4 Nanocrystals, Nanomaterials and Ring-Shaped Thermoelectric Generators
Liu, Y.; Garcia, G.; Ortega, S.; Cadavid, D.; Palacios, P.; Lu, J.; Ibanez, M.; Xi, L.; De Roo, J.; Lopez, A. M.; Marti, S.; Cabezas, I.; Mata, M. d. l.; Luo, Z.; Dun, C.; Dobrozhan, O.; Carroll, D.; Zhang, W.; Martins, J. C.; Kovalenko, M.; Arbiol, J.; Noriega, G.; Song, J.*; Wahnon Benarroch, P.*; Cabot, A.*
J. Mater. Chem. A 2017, 5 (6), 2592-2602; https://doi.org/10.1039/C6TA08467B

Microwave-assisted YBa2Cu3O7 precursors: A fast and reliable method towards chemical precursors for superconducting films
Rijckaert, H.; De Roo, J.; Roeleveld, K.; Pollefeyt, G.; Bennewitz, J.; Bäcker, M.; Lynen, F.; De Keukeleere, K.; Van Driessche, I.*
J. Am. Ceram. Soc. 2017, 100, 2407-2418; https://doi.org/10.1111/jace.14757

Optimizing Nanocomposites through Nanocrystal Surface Chemistry: Superconducting YBa2Cu3O7 Thin Films via Low-Fluorine Metal Organic Deposition and Preformed Metal Oxide Nanocrystals
Rijckaert, H.; Pollefeyt, G.; Sieger, M.; Hänisch, J.; Bennewitz, J.; De Keukeleere, K.; De Roo, J.; Hühne, R.; Bäcker, M.; Paturi, P.; Huhtinen, H.; Hemgesberg, M.; Van Driessche, I.*
Chem. Mater. 2017, 29, 6104-6113; https://doi.org/10.1021/acs.chemmater.7b02116

Diffusion (DOSY) 1H NMR as an alternative method for molecular weight determination of polyethylene furanoate (PEF) polyesters
Rosenboom, J. G.; De Roo, J.; Storti, G.; Morbidelli, M.*
Macromol. Chem. Phys.2017, 218 (1), 1600436; https://doi.org/10.1002/macp.201600436

Tuning Branching in Ceria Nanocrystals
Berestok, T.; Guardia, P.; Blanco, J.; Nafria, R.; Torruella, P.; Lopez-Conesa, L.; Estrade, S.; Ibáñez, M.; De Roo, J.; Luo, Z.; Cadavid, D.; Martins, J. C.; Kovalenko, M. V.; Peiró, F.*; Cabot, A.*
Chemistry of Materials2017, 9, 4418-4424; https://doi.org/10.1021/acs.chemmater.7b00896

Kinetic Control Over CdS Nanocrystal Nucleation Using a Library of Thiocarbonates, Thiocarbamates, and ThioureasHamachi, L. S.; Jen-La Plante, I.; Coryell, A. C.; De Roo, J., Owen, J. S.*Chem. Mater. 2017, 29, 8711-8719; doi.org/10.1021/acs.chemmater.7b02861

Stabilization of colloidal Ti, Zr, and Hf oxide nanocrystals by protonated tri-n-octylphosphine oxide (TOPO) and its decomposition products
De Keukeleere, K.; Coucke, C.; De Canck, E.; Van Der Voort, P.; Delpech, F.; Coppel, Y.; Hens, Z.; Van Driessche, I.; Owen, J. S.; De Roo, J.*
Chem. Mater.2017, 29, 10233-10242; https://doi.org/10.1021/acs.chemmater.7b04580

Insights in the ligand shell, the coordination mode and reactivity of carboxylic acid capped metal oxide nanocrystals
De Roo, J.*; Baquero, E.; Coppel, J.; De Keukeleere, K.; Van Driessche, I.; Nayral, C.; Hens, Z.; Delpech, F.*
ChemPlusChem 2016, 81 (11), 1216-1223; https://doi.org/10.1002/cplu.201600372

Colloidal metal oxide nanocrystal catalysis by sustained chemically driven ligand displacement
De Roo, J.*; Van Driessche, I.; Martins, J. C.; Hens, Z.*
Nat. Mater. 2016, 15 (5), 517-521; https://doi.org/10.1038/nmat4554

Highly Dynamic Ligand Binding and Light Absorption Coefficient of Cesium Lead Bromide Perovskite Nanocrystals
De Roo, J.; Ibáñez, M.; Geiregat, P.; Nedelcu, G.; Walravens, W.; Maes, J.; Martins, J. C.; Van Driessche, I.; Kovalenko, M.V.*; Hens, Z.*
ACS Nano 2016, 10 (2), 2071-2081; https://doi.org/10.1021/acsnano.5b06295

From ligands to binding motifs and beyond; the enhanced versatility of nanocrystal surfaces
De Roo, J.*; De Keukeleere, K.; Hens, Z.; Van Driessche, I.*
Dalton Trans. 2016, 45, 13277-13283; https://doi.org/10.1039/c6dt02410f

Revisited Wurtzite CdSe Synthesis: a Gateway for the Versatile Flash Synthesis of Multi-Shell Quantum Dots and Rods
Drijvers, E.; De Roo, J.; Geiregat, P.; Fehér, K.; Hens, Z.*; Aubert, T.*
Chem. Mater. 2016, 28 (20), 7311-7323; https://doi.org/10.1021/acs.chemmater.6b02666

Amino acid based stabilization of oxide nanocrystals in polar media; from insight in ligand exchange to solution 1H NMR probing of short–chained adsorbates
De Roo, J.*; Coucke, S.; Rijckaert, R.; De Keukeleere, K.; Sinnaeve, D.; Hens, Z.; Martins, J. C.; Van Driessche, I.*
Langmuir2016, 32, 1962-1970; https://doi.org/10.1021/acs.langmuir.5b04611

Superconducting YBa2Cu3O7-δ Nanocomposites Using Preformed ZrO2 Nanocrystals: Growth Mechanisms and Vortex Pinning Properties
De Keukeleere, K.; Cayado, P.; Meledin, A.; Vallès, F.; De Roo, J.; Rijckaert, H.; Pollefeyt, G.; Bruneel, E.; Palau, A.; Coll, M.; Ricart, S.; Van Tendeloo, G.; Puig, T.; Obradors, X.; Van Driessche, I.*
Adv. Electron. Mater. 2016, 2, 1600161; https://doi.org/10.1002/aelm.201600161

Chemically Triggered Formation of Epitaxial Quantum Dot Superlattices
Walravens, W., De Roo, J., Drijvers, E., ten Brinck, S., Minuesa, E., Dendooven, J., Detavernier, C., Infante, I., Hens., Z.*
ACS Nano
2016, 10 (7), 6861-6870; https://doi.org/10.1021/acsnano.6b02562

Colloidal AgSbSe2 nanocrystals: surface analysis, electronic doping and processing into efficient thermoelectric nanomaterials
Liu, Y.; Cadavid, D.; Ibáñez, M.; De Roo, J.; Ortega, S.; Dobrozhan, O.; Kovalenko, M.; Cabot, A.*
J. Mater. Chem. C
2016, 4, 4756-4762; https://doi.org/10.1039/c6tc00893c

Aminophosphines: a Double Role in the Synthesis of Colloidal Indium Phosphide Quantum Dots
Tessier, M.; De Nolf, K.; Dupont, D.; Sinnaeve, D.; De Roo, J.; Hens, Z.*
J. Am. Chem. Soc. 2016, 138 (18), 5923-5929; https://doi.org/10.1021/jacs.6b01254

Scalable heating-up procedure to synthesize monodisperse Cu2ZnSnS4 nanocrystals
Shavel, A.; Ibáñez, M.; Luo, Z.; De Roo, J.; Carrette, A.; Dimitrievska, M.; Genc, A.; Meyns, M.; Perez-Rodriguez, A.; Kovalenko, M. V., Arbiol, J.; Cabot, A.*
Chem. Mater.2016, 28 (3), 720-726; https://doi.org/10.1021/acs.chemmater.5b03417

The influence of tetraethoxysilane sol preparation on the electrospinning of silica nanofibers
Geltmeyer, J.; De Roo, J.; Van den Broeck, F.; Martins, J.; De Buysser, K.; De Clerck, K.*
J. Sol-Gel Sci. Technol.
2016, 77 (2), 453-462; https://doi.org/10.1007/s10971-015-3875-1

Carboxylic-Acid-Passivated Metal Oxide Nanocrystals: Ligand Exchange Characteristics of a New Binding Motif
De Roo, J.; Justo, Y.; De Keukeleere, K.; Van den Broeck, F.; Martins, J. C.; Van Driessche, I.; Hens, Z.*
Angew. Chem. Int. Ed. 2015, 54 (22), 6488-6491; https://doi.org/10.1002/anie.201500965

Epitaxial YBa2Cu3O7-x nanocomposite thin films from colloidal solutions
Cayado, P.; De Keukeleere, K.; Garzón, A.; Perez-Mirabet, L.; Meledin, A.; De Roo, J.; Valles, F.; Mundet, B.; Rijckaert, H.; Pollefeyt, G.; Coll Bau, M.; Ricart, S.; Palau, A.; Gazquez, J.; Ros, J.; Van Tendeloo, G.; Van Driessche, I.; Puig, T.; Obradors, X.*
Supercond. Sci. Technol. 2015, 28, 124007; https://doi.org/10.1088/0953-2048/28/12/124007

Economic and Size-tunable Synthesis of InP/ZnE (E = S,Se) Colloidal Quantum Dots
Tessier, M. D.; Dupont, D.; De Nolf, K.; De Roo, J.; Hens, Z.*
Chem. Mater.2015, 27, 4893-4898; https://doi.org/10.1021/acs.chemmater.5b02138

Fast and Tunable Synthesis of ZrO2 Nanocrystals: Mechanistic Insights into Precursor Dependence
De Keukeleere, K.; De Roo, J.; Lommens, P.; Martins, J. C.; Van der Voort, P.; Van Driessche, I.*
Inorg. Chem. 2015, 54 (7), 3469-3476; https://doi.org/10.1021/acs.inorgchem.5b00046

Chemical solution deposition of functional ceramic coatings using ink-jet printing
De Keukeleere, K.; Pollefeyt, G.; Feys, J.; De Roo, J.; Rijckaert, H.; Lommens, P.; Van Driessche, I.*
Pure Appl. Chem.2015, 87 (3), 231-238; https://doi.org/10.1515/pac-2014-0938

Unravelling the Surface Chemistry of Metal Oxide Nanocrystals, the Role of Acids and Bases
De Roo, J.; Van den Broeck, F.; De Keukeleere, K.; Martins, J. C.; Van Driessche, I.; Hens, Z.*
J. Am. Chem. Soc.2014, 136 (27), 9650-9657; https://doi.org/10.1021/ja5032979

 

Fast, microwave-assisted synthesis of monodisperse HfO2 nanoparticles
De Roo, J., De Keukeleere, K., Feys, J., Lommens, P., Hens, Z., Van Driessche, I.*
J Nanopart Res2013,15 (11), 1778; https://doi.org/10.1007/s11051-013-1778-z

Solution-based synthesis of BaZrO3 nanoparticles: conventional versus microwave synthesis
De Keukeleere, K., Feys, J., Meire, M., De Roo, J., De Buysser, K., Lommens, P., Van Driessche, I.*
J Nanopart Res2013,15, 2074; https://doi.org/10.1007/s11051-013-2074-7